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Creators/Authors contains: "Gholami, Hadi"

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  1. ; ; ; (, Accounts of Chemical Research)
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  2. ; ; ; ; ; (, Chemical Science)
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    A simple chiroptical solution for the absolute stereochemical determination for asymmetric phosphorus V stereocenters is presented. Strong coordination of the phosphorus oxide with the Zn-metallo center of the racemic host Zn-MAPOL 2 leads to an induced axial chirality of the host, yielding a strong ECCD signal. A mnemonic is proposed to correlate the asymmetry of the guest molecule with the observed ECCD signal. 
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